国外名校名著：化学和工程热力学（第3版）
NOTATION
CHAPTER
INTRODUCTION
1.1 The Central Problems of Thermodynamics
1.2 A System of Units
1.3 The Equilibrium State
1.4 Pressure， Temperature， and Equilibrium
1.5 Heat， Work， and the Conservation of Energy
1.6 Specification of the Equilibrium State; Intensive and Extensive
Variables; Equations of State
1.7 A Summary of Important Experimental Observations
1.8 A Comment on the Development of Thermodynamics
Problems
CHAPTER
CONSERVATION OF MASS AND ENERGY
2.1 A General Balance Equation and Conserved Quantities
2.2 Conservation of Mass
2.3 Conservation of Energy
2.4 The Thermodynamic Properties of Matter
2.5 Applications of the Mass and Energy Balances
2.6 Conservation of Momentum
2.7 The Microscopic Equations of Change for Thermodynamics and
Fluid Mechanics （Optional）
Problems
CHAPTER
ENTROPY： AN ADDITIONAL BALANCE EQUATION
3.1 Entropy： A New Concept
3.2 The Entropy Balance and Reversibility
3.3 Heat， Work， Engines， and Entropy
3.4 Entropy Changes of Matter
3.5 Applications of the Entropy Balance
3.6 Liquefaction
3.7 Power Generation and Refrigeration Cycles
3.8 The Thermodynamics of Mechanical Explosions
3.9 The Microscopic Entropy Balance （Optional）
Problems
CHAPTER
THE THERMODYNAMIC PROPERTIES OF REAL
SUBSTANCES
4.1 Some Mathematical Preliminaries
4.2 The Evaluation of Thermodynamic Partial Derivatives
4.3 The Ideal Gas and Absolute-Temperature Scales
4.4 The Evaluation of Changes in the Thermodynamic Properties of Real
Substances Accompanying a Change of State
4.5 An Example Involving the Change of State of a Real Gas
4.6 The Principle of Corresponding States
4.7 Generalized Equations of State
4.8 The Third Law of Thermodynamics
4.9 More About Thermodynamic Partial Derivatives （Optional）
Appendix A4.1 A Program for Thermodynamic Properties
Calculations Using the Peng-Robinson Cubic Equation
ofState， PR1
Problems
CHAPTER 5EQUILIBRIUM AND STABILITY IN ONE-COMPONENT
SYSTEMS
5.1 The Criteria for Equilibrium
5.2 Stability of Thermodynamic Systems
5.3 Phase Equilibria： Application of the Equilibrium and Stability
Criteria to the Equation of State
5.4 The Molar Gibbs Free Energy and Fugacity of a Pure
Component
5.5 The Calculation of Pure Fluid-Phase Equilibrium： The Computation
of Vapor Pressure from an Equation of State
5.6 The Specification of the Equilibrium Thermodynamic State of a
System of Several Phases： The Gibbs Phase Rule for a
One-Component System
5.7 Thermodynamic Properties of Phase Transitions
Problems
CHAPTER 6THE THERMODYNAMICS OF MULTICOMPONENT
MIXTURES
6.1 The Thermodynamic Description of Mixtures
6.2 The Partial Molar Gibbs Free Energy and the Generalized
Gibbs-Duhem Equation
6.3 A Notation for Chemical Reactions
6.4 The Equations of Change for a Multicomponent System
6.5 The Heat of Reaction and a Convention for the Thermodynamic
Properties of Reacting Mixtures
6.6 The Experimental Determination of the Partial Molar Volume and
Enthalpy
6.7 Criteria for Phase Equilibrium in Multicomponent Systems
6.8 The Criteria for Chemical Equilibrium， and Combined Chemical and
Phase Equilibrium
6.9 The Specification of the Equilibrium Thermodynamic State of a
Multicomponent， Multiphase System; the Gibbs Phase Rule
6.10 Some Concluding Remarks
Problems
CHAPTER 7THE ESTIMATION OF THE GIBBS FREE ENERGY AND
FUGACITY OF A COMPONENT IN A MIXTURE
7.1 The Ideal Gas Mixture
7.2 The Partial Molar Gibbs Free Energy and Fugacity
7.3 The Ideal Mixture and Excess Mixture Properties
7.4 The Fugacity of Species in Gaseous， Liquid， and Solid Mixtures
7.5 Several Correlative Liquid Mixture （Activity Coefficient）
Models
7.6 Two Predictive Activity Coefficient Models
7.7 A Corresponding States Principle for Mixtures; The Pseudocritical
Constant Method
7.8 The Fugacity of Species in Nonsimple Mixtures
7.9 Some Comments on Reference and Standard States
7.10 A Combined Equation-of-State--Excess Gibbs Free Energy
Models
7.11 Electrolyte Solutions
7.12 Concluding Remarks
Appendix A7.1 A Statistical Mechanical Interpretation of the Entropy of
Mixing in an Ideal Mixture
Appendix A7.2 A Program for Multicomponent Vapor-Liquid
Equilibrium Calculations Using the Peng-Robinson
Cubic Equation of State， VLMU
Appendix A7.3 Multicomponent Excess Gibbs Free Energy （Activity
Coefficient） Models
Appendix A7.4 A Program for the Prediction of Activity Coefficients
and Low Pressure Vapor-Liquid Equilibrium Using the
UNIFAC Model， UNIFAC.
Problems
CHAPTER 8 PHASE EQUILIBRIUM IN MIXTURESCHAPTER 9 CHEMICAL EQUILIBRIUM AND THE BALANCE
CHAPTER
INTRODUCTION
1.1 The Central Problems of Thermodynamics
1.2 A System of Units
1.3 The Equilibrium State
1.4 Pressure， Temperature， and Equilibrium
1.5 Heat， Work， and the Conservation of Energy
1.6 Specification of the Equilibrium State; Intensive and Extensive
Variables; Equations of State
1.7 A Summary of Important Experimental Observations
1.8 A Comment on the Development of Thermodynamics
Problems
CHAPTER
CONSERVATION OF MASS AND ENERGY
2.1 A General Balance Equation and Conserved Quantities
2.2 Conservation of Mass
2.3 Conservation of Energy
2.4 The Thermodynamic Properties of Matter
2.5 Applications of the Mass and Energy Balances
2.6 Conservation of Momentum
2.7 The Microscopic Equations of Change for Thermodynamics and
Fluid Mechanics （Optional）
Problems
CHAPTER
ENTROPY： AN ADDITIONAL BALANCE EQUATION
3.1 Entropy： A New Concept
3.2 The Entropy Balance and Reversibility
3.3 Heat， Work， Engines， and Entropy
3.4 Entropy Changes of Matter
3.5 Applications of the Entropy Balance
3.6 Liquefaction
3.7 Power Generation and Refrigeration Cycles
3.8 The Thermodynamics of Mechanical Explosions
3.9 The Microscopic Entropy Balance （Optional）
Problems
CHAPTER
THE THERMODYNAMIC PROPERTIES OF REAL
SUBSTANCES
4.1 Some Mathematical Preliminaries
4.2 The Evaluation of Thermodynamic Partial Derivatives
4.3 The Ideal Gas and Absolute-Temperature Scales
4.4 The Evaluation of Changes in the Thermodynamic Properties of Real
Substances Accompanying a Change of State
4.5 An Example Involving the Change of State of a Real Gas
4.6 The Principle of Corresponding States
4.7 Generalized Equations of State
4.8 The Third Law of Thermodynamics
4.9 More About Thermodynamic Partial Derivatives （Optional）
Appendix A4.1 A Program for Thermodynamic Properties
Calculations Using the Peng-Robinson Cubic Equation
ofState， PR1
Problems
CHAPTER 5EQUILIBRIUM AND STABILITY IN ONE-COMPONENT
SYSTEMS
5.1 The Criteria for Equilibrium
5.2 Stability of Thermodynamic Systems
5.3 Phase Equilibria： Application of the Equilibrium and Stability
Criteria to the Equation of State
5.4 The Molar Gibbs Free Energy and Fugacity of a Pure
Component
5.5 The Calculation of Pure Fluid-Phase Equilibrium： The Computation
of Vapor Pressure from an Equation of State
5.6 The Specification of the Equilibrium Thermodynamic State of a
System of Several Phases： The Gibbs Phase Rule for a
One-Component System
5.7 Thermodynamic Properties of Phase Transitions
Problems
CHAPTER 6THE THERMODYNAMICS OF MULTICOMPONENT
MIXTURES
6.1 The Thermodynamic Description of Mixtures
6.2 The Partial Molar Gibbs Free Energy and the Generalized
Gibbs-Duhem Equation
6.3 A Notation for Chemical Reactions
6.4 The Equations of Change for a Multicomponent System
6.5 The Heat of Reaction and a Convention for the Thermodynamic
Properties of Reacting Mixtures
6.6 The Experimental Determination of the Partial Molar Volume and
Enthalpy
6.7 Criteria for Phase Equilibrium in Multicomponent Systems
6.8 The Criteria for Chemical Equilibrium， and Combined Chemical and
Phase Equilibrium
6.9 The Specification of the Equilibrium Thermodynamic State of a
Multicomponent， Multiphase System; the Gibbs Phase Rule
6.10 Some Concluding Remarks
Problems
CHAPTER 7THE ESTIMATION OF THE GIBBS FREE ENERGY AND
FUGACITY OF A COMPONENT IN A MIXTURE
7.1 The Ideal Gas Mixture
7.2 The Partial Molar Gibbs Free Energy and Fugacity
7.3 The Ideal Mixture and Excess Mixture Properties
7.4 The Fugacity of Species in Gaseous， Liquid， and Solid Mixtures
7.5 Several Correlative Liquid Mixture （Activity Coefficient）
Models
7.6 Two Predictive Activity Coefficient Models
7.7 A Corresponding States Principle for Mixtures; The Pseudocritical
Constant Method
7.8 The Fugacity of Species in Nonsimple Mixtures
7.9 Some Comments on Reference and Standard States
7.10 A Combined Equation-of-State--Excess Gibbs Free Energy
Models
7.11 Electrolyte Solutions
7.12 Concluding Remarks
Appendix A7.1 A Statistical Mechanical Interpretation of the Entropy of
Mixing in an Ideal Mixture
Appendix A7.2 A Program for Multicomponent Vapor-Liquid
Equilibrium Calculations Using the Peng-Robinson
Cubic Equation of State， VLMU
Appendix A7.3 Multicomponent Excess Gibbs Free Energy （Activity
Coefficient） Models
Appendix A7.4 A Program for the Prediction of Activity Coefficients
and Low Pressure Vapor-Liquid Equilibrium Using the
UNIFAC Model， UNIFAC.
Problems
CHAPTER 8 PHASE EQUILIBRIUM IN MIXTURESCHAPTER 9 CHEMICAL EQUILIBRIUM AND THE BALANCE
STANLEY I.SANDLER earned the B．Ch．E．degree in 1962 from the City College of New Y0rk．and the Ph．D．in chemical engineering from the University of Minnesota in 1966．He was then a National Science Foundation Postdoctoral Fellow at the Institute for Molecular Physics at the University of Maryland for the 1966-67 academic year．He joined the faculty of the University of Delaware in 1967 as all assistant professor，and was promoted to associate professor in 1970．professor in 1973 and Henry Belin du Pont Professor of Chemical Engineering in 1982．He was department chairman from 1 982 to 1986．He currently is also professor of chemistry and biochemistry at the University of Delaware and founding director of its Center for Molecular and Engineering Thermodynamics．He has been a visiting professor at Imperial College(London)，the Technical University of Berlin．the University of Queensland(Australia)and the University of California．Berkeley．
In addition to this book．Professor Sandier is the author of 225 research papers and a monograph，and he is the editor of a book on thermodynamic modeling and five conference proceedings．Among his many awards and honors are a Faculty Scholar Award(1971)from the Camille and Henry Dreyfus Foundation，a Research Fellow-ship(1980)and US．Senior Scientist Award(1988)from the Alexander von Humboldt Foundation(Germany)，the 3M Chemical Engineering Lectureship Award (1988)from the American Society for Engineering Education，the Professional Progress(1984)and Warren K．Lewis Awards(1996)from the American Institute of Chemical Engineers，the E．V Murphree Award(1996)from the American Chemical Society, the Rossini Lectureship Award(1 997)from the International Union of Pure and Applied Chemistry, and election to the US．National Academy of Engineering
In addition to this book．Professor Sandier is the author of 225 research papers and a monograph，and he is the editor of a book on thermodynamic modeling and five conference proceedings．Among his many awards and honors are a Faculty Scholar Award(1971)from the Camille and Henry Dreyfus Foundation，a Research Fellow-ship(1980)and US．Senior Scientist Award(1988)from the Alexander von Humboldt Foundation(Germany)，the 3M Chemical Engineering Lectureship Award (1988)from the American Society for Engineering Education，the Professional Progress(1984)and Warren K．Lewis Awards(1996)from the American Institute of Chemical Engineers，the E．V Murphree Award(1996)from the American Chemical Society, the Rossini Lectureship Award(1 997)from the International Union of Pure and Applied Chemistry, and election to the US．National Academy of Engineering
随着中国社会主义现代化建设进入新的阶段，以高质量的高等教育培养千百万专门人才，迎接新世纪的挑战，是实现“科教兴国”战略的基础工程，也是完成“十五”计划各项奋斗目标的重要保证。为切实加强高等学校本科教学并提高教学质量，教育部于2001年专门下发文件提出12条意见，对高等学校教学工作从认识、管理、教师队伍到教学方法和教学手段等给予指导。文件强调，按照“教育要面向现代化、面向世界、面向未来”的要求，为适应经济全球化和科技国际化的挑战，本科教育要创造条件使用英语等外语进行公共课和专业课教学。
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以其化学化工专业领域的优势资源为基础，化学工业出版社的教材引进主要涉及化学、化学工程与工艺、环境科学与工程、生物技术与工程、材料科学与工程、制药工程等专业，对过程装备与控制工程、自动化等传统专业教材的引进也在规划之中。
在文件精神指导下，全国普通高等学校尤其是重点高校中兴起了使用国外教材开展教学活动的潮流。如生物技术与工程、环境科学与工程、材料科学与工程及作为其学科基础理论重要组成部分的化学技术和化学工程技术又是这股潮流中最为活跃的领域之一。在教育部“化工类专业人才培养方案及教学内容体系改革的研究与实践”项目组及“化工类专业创新人才培养模式、教学内容、教学方法和教学技术改革的研究与实践”项目组和“全国本科化学工程与工艺专业教学指导委员会”的指导和支持下，化学工业出版社及时启动了引进国外名校名著的教材工程。
出版社组织编辑人员多次赴国外学习考察，通过国外出版研究机构对国外著名的高等学校进行调查研究，搜集了一大批国际知名院校的现用教材选题。他们还联络国内重点高校的专家学者组建了“国外名校名著评价委员会”，对国外和国内高等本科教学进行比较研究，对教材内容质量进行审查评议，然后决定是否引进。他们与国外许多著名的出版机构建立了联系，有的还建立了长期合作关系，以掌握世界范围内优秀教材的出版动态。
以其化学化工专业领域的优势资源为基础，化学工业出版社的教材引进主要涉及化学、化学工程与工艺、环境科学与工程、生物技术与工程、材料科学与工程、制药工程等专业，对过程装备与控制工程、自动化等传统专业教材的引进也在规划之中。
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